Exact Differential - Some Useful Equations Derived From Exact Differentials in Two Dimensions | Equations Derived Exact Differentials Dimensions

Some Useful Equations Derived From Exact Differentials in Two Dimensions

(See also Bridgman's thermodynamic equations for the use of exact differentials in the theory of thermodynamic equations)

Suppose we have five state functions, and . Suppose that the state space is two dimensional and any of the five quantities are exact differentials. Then by the chain rule

$(1)~~~~~ dz = \left(\frac{\partial z}{\partial x}\right)_y dx+ \left(\frac{\partial z}{\partial y}\right)_x dy = \left(\frac{\partial z}{\partial u}\right)_v du +\left(\frac{\partial z}{\partial v}\right)_u dv$

but also by the chain rule:

$(2)~~~~~ dx = \left(\frac{\partial x}{\partial u}\right)_v du +\left(\frac{\partial x}{\partial v}\right)_u dv$

and

$(3)~~~~~ dy= \left(\frac{\partial y}{\partial u}\right)_v du +\left(\frac{\partial y}{\partial v}\right)_u dv$

so that:

$(4)~~~~~ dz = \left[ \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial u}\right)_v + \left(\frac{\partial z}{\partial y}\right)_x \left(\frac{\partial y}{\partial u}\right)_v \right]du$

$+ \left[ \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial v}\right)_u + \left(\frac{\partial z}{\partial y}\right)_x \left(\frac{\partial y}{\partial v}\right)_u \right]dv$

which implies that:

$(5)~~~~~ \left(\frac{\partial z}{\partial u}\right)_v = \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial u}\right)_v + \left(\frac{\partial z}{\partial y}\right)_x \left(\frac{\partial y}{\partial u}\right)_v$

Letting gives:

$(6)~~~~~ \left(\frac{\partial z}{\partial u}\right)_y = \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial u}\right)_y$

Letting gives:

$(7)~~~~~ \left(\frac{\partial z}{\partial y}\right)_v = \left(\frac{\partial z}{\partial y}\right)_x + \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial y}\right)_v$

Letting, gives:

$(8)~~~~~ \left(\frac{\partial z}{\partial y}\right)_x = - \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial y}\right)_z$

using ( $\partial a/\partial b)_c = 1/(\partial b/\partial a)_c$ gives the triple product rule:

$(9)~~~~~ \left(\frac{\partial z}{\partial x}\right)_y \left(\frac{\partial x}{\partial y}\right)_z \left(\frac{\partial y}{\partial z}\right)_x =-1$

Read more about this topic: Exact Differential

Famous quotes containing the words derived, exact and/or dimensions:

“Jesus wept; Voltaire smiled. From that divine tear and from that human smile is derived the grace of present civilization.”
—Victor Hugo (1802–1885)

“Men are qualified for civil liberty in exact proportion to their disposition to put moral chains upon their own appetites; in proportion as their love to justice is above their rapacity; in proportion as their soundness and sobriety of understanding is above their vanity and presumption; in proportion as they are more disposed to listen to the counsels of the wise and good, in preference to the flattery of knaves.”
—Edmund Burke (1729–1797)

“Is it true or false that Belfast is north of London? That the galaxy is the shape of a fried egg? That Beethoven was a drunkard? That Wellington won the battle of Waterloo? There are various degrees and dimensions of success in making statements: the statements fit the facts always more or less loosely, in different ways on different occasions for different intents and purposes.”
—J.L. (John Langshaw)