Electric Potential - Galvani Potential Versus Electrochemical Potential

Galvani Potential Versus Electrochemical Potential

Inside metals (and other solids and liquids), the energy of an electron is affected not only by the electric potential, but also by the specific atomic environment that it is in. When a voltmeter is connected between two different types of metal, it measures not the electric potential difference, but instead the potential difference corrected for the different atomic environments. The quantity measured by a voltmeter is called electrochemical potential or fermi level, while the pure unadjusted electric potential is sometimes called Galvani potential. The terms "voltage" and "electric potential" are a bit ambiguous in that, in practice, they can refer to either of these in different contexts.