Eduard Study - Valence Theory

Valence Theory

Somewhat surprisingly Eduard Study is known by practitioners of quantum chemistry. Like James Joseph Sylvester, Paul Gordan believed that invariant theory could contribute to the understanding of chemical valence. In 1900 Gordan and his student G. Alexejeff contributed an article on an analogy between the coupling problem for angular momenta and their work on invariant theory to the Zeitschrift für Physikalische Chemie (v. 35, p. 610). In 2006 Wormer and Paldus summarized Study's role as follows:

The analogy, lacking a physical basis at the time, was criticised heavily by the mathematician E. Study and ignored completely by the chemistry community of the 1890's. After the advent of quantum mechanics it became clear, however, that chemical valences arise from electron-spin couplings ... and that electron spin functions are, in fact, binary forms of the type studied by Gordan and Clebsch.