Dissociation Constant of Water
As a frequently used special case, the dissociation constant of water is often expressed as Kw:
The concentration of water is not included in the definition of Kw, for reasons described in the article equilibrium constant.
The value of Kw varies with temperature, as shown in the table below. This variation must be taken into account when making precise measurements of quantities such as pH.
| Water temperature | Kw / 10−14 | pKw |
|---|---|---|
| 0°C | 0.1 | 14.92 |
| 10°C | 0.3 | 14.52 |
| 18°C | 0.7 | 14.16 |
| 25°C | 1.2 | 13.92 |
| 30°C | 1.8 | 13.75 |
| 50°C | 8.0 | 13.10 |
| 60°C | 12.6 | 12.90 |
| 70°C | 21.2 | 12.67 |
| 80°C | 35 | 12.46 |
| 90°C | 53 | 12.28 |
| 100°C | 73 | 12.14 |
Read more about this topic: Dissociation Constant
Famous quotes containing the words constant and/or water:
“Justice is the set and constant purpose which gives every man his due.”
—Marcus Tullius Cicero (106–43 B.C.)
“Not all the water in the rough rude sea
Can wash the balm off from an anointed king;
The breath of worldly men cannot depose
The deputy elected by the Lord.”
—William Shakespeare (1564–1616)