Reagent in Organic Synthesis
Diborane is the central organic synthesis reagent for hydroboration, whereby alkenes add across the B-H bonds to give trialkylboranes:
- (THF)BH3 + 3 CH2=CHR → B(CH2CH2R)3 + THF
This reaction is regioselective, and the product trialkylboranes can be converted to useful organic derivatives. With bulky alkenes one can prepare species such as 2, which are also useful reagents in more specialized applications.
Diborane is used as a reducing agent roughly complementary to the reactivity of lithium aluminium hydride. The compound readily reduces carboxylic acids to the corresponding alcohols, whereas ketones react only sluggishly.
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