The principle of detailed balance is formulated for kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions): At equilibrium, each elementary process should be equilibrated by its reverse process.
Read more about Detailed Balance: History, Microscopical Background, Reversible Markov Chains, Detailed Balance and The Entropy Growth, Wegscheider's Conditions For The Generalized Mass Action Law, Dissipation in Systems With Detailed Balance, Onsager Reciprocal Relations and Detailed Balance, Semi-detailed Balance, Dissipation in Systems With Semi-detailed Balance, Detailed Balance For Systems With Irreversible Reactions
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