Synthesis, Basic Properties, Structure
Although the formula is written CNCl, cyanogen chloride is a molecule with the connectivity ClCN. Carbon and chlorine are linked by a single bond, and carbon and nitrogen by a triple bond. It is a linear molecule, as are the related cyanogen halides (NCF, NCBr, NCI). Cyanogen chloride is produced by the oxidation of sodium cyanide with chlorine. This reaction proceeds via the intermediate cyanogen ((CN)2).
- NaCN + Cl2 → ClCN + NaCl
The compound trimerizes in the presence of acid to the heterocycle called cyanuric chloride.
Cyanogen chloride is slowly hydrolyzed by water to release hydrogen cyanide
- ClCN + H2O → HCN + HOCl
Read more about this topic: Cyanogen Chloride
Famous quotes containing the words basic and/or structure:
“... in Northern Ireland, if you don’t have basic Christianity, rather than merely religion, all you get out of the experience of living is bitterness.”
—Bernadette Devlin (b. 1947)
“I really do inhabit a system in which words are capable of shaking the entire structure of government, where words can prove mightier than ten military divisions.”
—Václav Havel (b. 1936)