Correspondence Principle - Quantum Mechanics

Quantum Mechanics

The rules of quantum mechanics are highly successful in describing microscopic objects, atoms and elementary particles. But macroscopic systems, like springs and capacitors, are accurately described by classical theories like classical mechanics and classical electrodynamics. If quantum mechanics were to be applicable to macroscopic objects, there must be some limit in which quantum mechanics reduces to classical mechanics. Bohr's correspondence principle demands that classical physics and quantum physics give the same answer when the systems become large.

The conditions under which quantum and classical physics agree are referred to as the correspondence limit, or the classical limit. Bohr provided a rough prescription for the correspondence limit: it occurs when the quantum numbers describing the system are large. A more elaborated analysis of quantum-classical correspondence (QCC) in wavepacket spreading leads to the distinction between robust "restricted QCC" and fragile "detailed QCC". "Restricted QCC" refers to the first two moments of the probability distribution and is true even when the wave packets diffract, while "detailed QCC" requires smooth potentials which vary over scales much larger than the wavelength, which is what Bohr considered.

The post-1925 new quantum theory came in two different formulations. In matrix mechanics, the correspondence principle was built in and was used to construct the theory. In the Schrödinger approach classical behavior is not clear because the waves spread out as they move. Once the Schrödinger equation was given a probabilistic interpretation, Ehrenfest showed that Newton's laws hold on average: the quantum statistical expectation value of the position and momentum obey Newton's laws.

The correspondence principle is one of the tools available to physicists for selecting quantum theories corresponding to reality. The principles of quantum mechanics are broad: states of a physical system form a complex vector space and physical observables are identified with Hermitian operators that act on this Hilbert space. The correspondence principle limits the choices to those that reproduce classical mechanics in the correspondence limit.

Because quantum mechanics only reproduces classical mechanics in a statistical interpretation, and because the statistical interpretation only gives the probabilities of different classical outcomes, Bohr has argued that classical physics does not emerge from quantum physics in the same way that classical mechanics emerges as an approximation of special relativity at small velocities. He argued that classical physics exists independently of quantum theory and cannot be derived from it. His position is that it is inappropriate to understand the experiences of observers using purely quantum mechanical notions such as wavefunctions because the different states of experience of an observer are defined classically, and do not have a quantum mechanical analog. The relative state interpretation of quantum mechanics is an attempt to understand the experience of observers using only quantum mechanical notions. Niels Bohr was an early opponent of such interpretations.

Many of these conceptual problems, however, resolve in the phase-space formulation of quantum mechanics, where the same variables with the same interpretation are utilized to describe both quantum and classical mechanics.