Graphs
Graphs have path connected subsets, namely those subsets for which every pair of points has a path of edges joining them. But it is not always possible to find a topology on the set of points which induces the same connected sets. The 5-cycle graph (and any n-cycle with n>3 odd) is one such example.
As a consequence, a notion of connectedness can be formulated independently of the topology on a space. To wit, there is a category of connective spaces consisting of sets with collections of connected subsets satisfying connectivity axioms; their morphisms are those functions which map connected sets to connected sets (Muscat & Buhagiar 2006). Topological spaces and graphs are special cases of connective spaces; indeed, the finite connective spaces are precisely the finite graphs.
However, every graph can be canonically made into a topological space, by treating vertices as points and edges as copies of the unit interval (see topological graph theory#Graphs as topological spaces). Then one can show that the graph is connected (in the graph theoretical sense) if and only if it is connected as a topological space.
Read more about this topic: Connected Space