Compressibility Factor - Experimental Values

Experimental Values

It is extremely difficult to generalize at what pressures or temperatures the deviation from the ideal gas becomes important. As a rule of thumb, the ideal gas law is reasonably accurate up to a pressure of about 2 atm, and even higher for small non-associating molecules. For example methyl chloride, a highly polar molecule and therefore with significant intermolecular forces, the experimental value for the compressibility factor is at a pressure of 10 atm and temperature of 100 °C. For air (small non-polar molecules) at approximately the same conditions, the compressibility factor is only (see table below for 10 bars, 400 K).

Read more about this topic:  Compressibility Factor

Famous quotes containing the words experimental and/or values:

    Philosophers of science constantly discuss theories and representation of reality, but say almost nothing about experiment, technology, or the use of knowledge to alter the world. This is odd, because ‘experimental method’ used to be just another name for scientific method.... I hope [to] initiate a Back-to-Bacon movement, in which we attend more seriously to experimental science. Experimentation has a life of its own.
    Ian Hacking (b. 1936)

    Autonomy means women defining themselves and the values by which they will live, and beginning to think of institutional arrangements which will order their environment in line with their needs.... Autonomy means moving out from a world in which one is born to marginality, to a past without meaning, and a future determined by others—into a world in which one acts and chooses, aware of a meaningful past and free to shape one’s future.
    Gerda Lerner (b. 1920)