Chromic Acid - Reactions

Reactions

Chromic acid is capable of oxidizing many kinds of organic compounds and many variations on this reagent have been developed:

  • Chromic acid in aqueous sulfuric acid and acetone is known as the Jones reagent, which will oxidize primary and secondary alcohols to carboxylic acids and ketones respectively, while rarely affecting unsaturated bonds.
  • Pyridinium chlorochromate is generated from chromium trioxide and pyridinium chloride. This reagent converts primary alcohols to the corresponding aldehydes (R-CHO).
  • Collins reagent is an adduct of chromium trioxide and pyridine used for diverse oxidations.
  • Chromyl chloride, CrO2Cl2 is a well-defined molecular compound that is generated from chromic acid.

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