Bessemer Process - History

History

In 1740 Benjamin Huntsman developed the crucible technique for steel manufacture, at his workshop in the district of Handsworth in Sheffield. This process had an enormous impact on the quantity and quality of steel production.

Sir Henry Bessemer described the origin of his invention in Chapters 10 and 11 of his autobiography. According to this book at the time of the outbreak of the Crimean War many English industrialists and inventors became interested in military technology and Bessemer himself developed a method for grooving artillery projectiles so that they could spin without the use of rifling in the bore of the gun. He patented this method in 1854 and began developing it in conjunction with the government of France. After a successful day of testing of his method at the Polygon in France he had a conversation with Claude-Étienne Minié who stated that a key barrier to the use of the larger, heavier spinning projectiles would be the strength of the gun and in particular "...he did not consider it safe in practice to fire a 30-lb. shot from a 12-pounder cast-iron gun. The real question, he said, was; Could any guns be made to stand such heavy projectiles?". This is what started Bessemer thinking about steel. At the time steel was difficult and expensive to make and was consequently used in only small items like cutlery and tools. Starting in January 1855 he began working on a way to produce steel in the massive quantities required for artillery and by October he filed his first patent related to the Bessemer process.

According to his autobiography Bessemer was working with an ordinary reverbatory furnace but during a test, some pieces of pig iron were jostled off the side of the ladle, and were left above the ladle in the furnace's heat. When Bessemer went to push them into the ladle, he found that they were steel shells: the hot air alone had converted the outsides of the iron pieces to steel. This crucial discovery led him to completely redesign his furnace so that it would force high-pressure air through the molten iron using special air pumps. Intuitively this would seem to be folly because it would cool the iron. Instead, the oxygen in the forced air ignited silicon and carbon impurities in the iron, starting a positive feedback loop. As the iron became hotter, more impurities burned off, making the iron even hotter and burning off more impurities, producing a batch of hotter, purer, molten iron, which converts to steel more easily.

Bessemer licensed the patent for his process to four ironmasters, for a total of £27,000, but the licensees failed to produce the quality of steel he had promised—it was "rotten hot and rotten cold", according to his friend, William Clay—and he later bought them back for £32,500. His plan had been to offer the licenses to one company in each of several geographic areas, at a royalty price per ton that included a lower rate on a proportion of their output in order to encourage production, but not so large a proportion that they might decide to reduce their selling prices. By this method he hoped to cause the new process to gain in standing and market share.

He realised that the technical problem was due to impurities in the iron and concluded that the solution lay in knowing when to turn off the flow of air in his process so that the impurities were burned off but just the right amount of carbon remained. However, despite spending tens of thousands of pounds on experiments, he could not find the answer. Certain grades of steel are sensitive to the 78% nitrogen which was part of the air blast passing through the steel.

The solution was first discovered by English metallurgist Robert Forester Mushet, who had carried out thousands of experiments in the Forest of Dean. His method was to first burn off, as far as possible, all the impurities and carbon, then reintroduce carbon and manganese by adding an exact amount of spiegeleisen. This had the effect of improving the quality of the finished product, increasing its malleability—its ability to withstand rolling and forging at high temperatures and making it more suitable for a vast array of uses.

The first company to license the process was the Manchester firm of W & J Galloway, and they did so before Bessemer announced it at Cheltenham in 1856. They are not included in his list of the four to whom he refunded the license fees. However, they subsequently rescinded their license in 1858 in return for the opportunity to invest in a partnership with Bessemer and others. This partnership began to manufacture steel in Sheffield from 1858, initially using imported charcoal pig iron from Sweden. This was the first commercial production.