Explanation of The General Trends
The way the atomic radius varies with increasing atomic number can be explained by the arrangement of electrons in shells of fixed capacity. The shells are generally filled in order of increasing radius, since the negatively charged electrons are attracted by the positively charged protons in the nucleus. As the atomic number increases along each row of the periodic table, the additional electrons go into the same outermost shell; whose radius gradually contracts, due to the increasing nuclear charge. In a noble gas, the outermost shell is completely filled; therefore, the additional electron of next alkali metal will go into the next outer shell, accounting for the sudden increase in the atomic radius.
The increasing nuclear charge is partly counterbalanced by the increasing number of electrons, a phenomenon that is known as shielding; which explains why the size of atoms usually increases down each column. However, there is one notable exception, known as the lanthanide contraction: the 5d block of elements are much smaller than one would expect, due to the shielding caused by the 4f electrons.
The following table summarizes the main phenomena that influence the atomic radius of an element:
| factor | principle | increase with... | tend to | effect on radius |
|---|---|---|---|---|
| electron shells | quantum mechanics | principal and azimuthal quantum numbers | increase atomic radius | increases down each column |
| nuclear charge | attractive force acting on electrons by protons in nucleus | atomic number | decrease atomic radius | decreases along each period |
| shielding | repulsive force acting on outermost shell electrons by inner electrons | number of electron shells | increase atomic radius | reduces the effect of the 2nd factor |
Read more about this topic: Atomic Radius
Famous quotes containing the words explanation of the, explanation of, explanation, general and/or trends:
“What causes adolescents to rebel is not the assertion of authority but the arbitrary use of power, with little explanation of the rules and no involvement in decision-making. . . . Involving the adolescent in decisions doesn’t mean that you are giving up your authority. It means acknowledging that the teenager is growing up and has the right to participate in decisions that affect his or her life.”
—Laurence Steinberg (20th century)
“What causes adolescents to rebel is not the assertion of authority but the arbitrary use of power, with little explanation of the rules and no involvement in decision-making. . . . Involving the adolescent in decisions doesn’t mean that you are giving up your authority. It means acknowledging that the teenager is growing up and has the right to participate in decisions that affect his or her life.”
—Laurence Steinberg (20th century)
“To develop an empiricist account of science is to depict it as involving a search for truth only about the empirical world, about what is actual and observable.... It must involve throughout a resolute rejection of the demand for an explanation of the regularities in the observable course of nature, by means of truths concerning a reality beyond what is actual and observable, as a demand which plays no role in the scientific enterprise.”
—Bas Van Fraassen (b. 1941)
“‘A thing is called by a certain name because it instantiates a certain universal’ is obviously circular when particularized, but it looks imposing when left in this general form. And it looks imposing in this general form largely because of the inveterate philosophical habit of treating the shadows cast by words and sentences as if they were separately identifiable. Universals, like facts and propositions, are such shadows.”
—David Pears (b. 1921)
“A point has been reached where the peoples of the Americas must take cognizance of growing ill-will, of marked trends toward aggression, of increasing armaments, of shortening tempers—a situation which has in it many of the elements that lead to the tragedy of general war.... Peace is threatened by those who seek selfish power.”
—Franklin D. Roosevelt (1882–1945)