Qualified Teams
| Association | Team | Qualification method |
|---|---|---|
| Argentina |
Boca Juniors | 2005 Apertura and 2006 Clausura champion |
| Gimnasia y Esgrima (LP) | 2005–06 best placed team on aggregate table | |
| River Plate | 2005–06 2nd best placed team on aggregate table | |
| Banfield | 2005–06 3rd best placed team on aggregate table | |
| Vélez Sársfield | 2005–06 4th best placed team on aggregate table | |
| Bolivia |
Blooming | 2005 Apertura champion |
| Bolívar | 2006 Apertura champion | |
| Real Potosí | 2006 Apertura runner-up | |
| Brazil |
Internacional | 2006 Copa Libertadores champion |
| Flamengo | 2006 Copa do Brasil champion | |
| São Paulo | 2006 Série A champion | |
| Grêmio | 2006 Série A 3rd place | |
| Santos | 2006 Série A 4th place | |
| Paraná | 2006 Série A 5th place | |
| Chile |
Colo-Colo | 2006 Apertura and 2006 Clausura champion |
| Audax Italiano | 2006 Clausura finalist | |
| Cobreloa | Best-placed team in the 2006 Clausura classification stage | |
| Colombia |
Deportivo Pasto | 2006 Apertura champion |
| Cúcuta Deportivo | 2006 Clausura champion | |
| Deportes Tolima | 2006 best placed team on aggregate table | |
| Ecuador |
El Nacional | 2006 Seria A champion |
| Emelec | 2006 Seria A runner-up | |
| LDU Quito | 2006 Seria A 3rd place | |
| Paraguay |
Libertad | 2006 Primera División champion |
| Cerro Porteño | 2006 Primera División runner-up | |
| Tacuary | 2006 best placed team on aggregate table | |
| Peru |
Alianza Lima | 2006 Apertura winner |
| Cienciano | 2006 Clausura winner | |
| Sporting Cristal | 2006 best placed team on aggregate table | |
| Uruguay |
Nacional | 2005–06 Primera División champion |
| Defensor Sporting | 2006 Liguilla Pre-Libertadores winner | |
| Danubio | 2006 Liguilla Pre-Libertadores runner-up | |
| Venezuela |
Caracas | 2005–06 Primera División champion |
| Maracaibo | 2005–06 Primera División runner-up | |
| Deportivo Táchira | 2005–06 best placed team on aggregate table | |
| Mexico |
Toluca | 2005 Apertura champion |
| Necaxa | 2007 InterLiga winner | |
| América | 2007 InterLiga runner-up |
Read more about this topic: 2007 Copa Libertadores
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